When it is dark, do the City Alert one time.
Successfully complete the game as Spider-Man to unlockSymbiote Spider-Man's story mode and Arena mode.
Successfully complete the game to unlock the Arena mode optionin the Extras menu.
Collect all 50 Black Spider Tokens to get the black Spider-Mansuit to wear whenever desired for as long as you want.
As Black suit Spider-Man, use your slow motion to dodgethe King-Pin's attacks. Build up your "Rage Mode". Oncein "Rage Mode" you can attack as normal.
When facing Kingpin, tap X to jump up in the air. Do not hold X or you will jump too high. While in the air, keep tapping Triangle. It will take awhile to build up rage. Once rage is built up, quickly tap R1 to go into Rage mode in the air. While in Rage mode and in the air keep tapping Triangle to hit Kingpin. If you stay away from the walls by using the Left Analog-stick to move Spider-man, Kingpin will never hit you.