Bleach Wii: Hakujin Kirameku Rondo

Defeat Arturo Plateado on the final stage of episode mode.

Clear Arcade Mode with Toushiro Hitsugaya.

Complete Hitsugaya's episode mode.

Clear Arcade Mode with Madarame Ikkaku again after unlocking all characters.

Clear Arcade Mode with Abarai Renji.

Clear Arcade mode with Shihouin Yoruichi and complete the Tutorial mode.

Unlockable - How to Unlock

Aizen Sousuke - Clear Arcade Mode with Ulquiorra
Arturo Plateado - Unknown; in relation to Story Mode
Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
Hinamori Momo - Unknown; in relation to Story Mode
Hisagi Shuuhei - Unknown; in relation to Story Mode
Ichimaru Gin - Clear Arcade Mode with Matsumoto Rangiku
Kuchiki Rukia - Unknown; in relation to Story Mode
Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
Kusajishi Yachiru - Clear Arcade Mode with Yumichika Ayasegawa
Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
Madarame Ikkaku - Unknown; in relation to Story Mode
Shihouin Yoruichi - Clear Training Mode
Soi Fon - Unknown; in relation to Story Mode
Tousen Kaname - Clear Arcade Mode with Komamura Sajin
Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
Ulquiorra - Clear Arcade Mode with Ichimaru Gin
Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
Yamada Hanatarou - Unknown; in relation to Story Mode
Yamamoto Genryuusai Shigekuni - Clear Arcade Mode with Ukitake Juushiro
Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku

Unlock Everything.

Clear Arcade Mode with Ayasegawa Yumichika again after unlocking all characters.