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The following attires become unlocked when you complete the corresponding task in the indicated chapter of Attitude Era mode on any difficulty setting.

Bradshaw APA Attire:
Unlocked in the 'Off Script' chapter.

Faarooq APA Attire:
Unlocked in the 'Off Script' chapter.

Kane '97-99 Debut Lighting:
Unlocked in the 'Rise Of DX' chapter.

Kane '97-99 Two Sleeves Attire:
Unlocked in the 'Brothers Of Destruction' chapter.

Kane '97-99 Undertaker Disguise:
Unlocked in the 'Brothers Of Destruction' chapter.

Mankind Brown Attire:
Unlocked in the 'Rise Of DX' chapter.

Stone Cold 3:16 T-Shirt:
Unlocked in the 'Brothers Of Destruction' chapter.

The Rock '98-99 Work-Out Attire:
Unlocked in the 'Mankind' chapter.

In the Atitude Era mode unlockables there are some extras.

The following movesets correspond to the indicated character.

Moveset 1: Evan Bourne
Moveset 2: Alex Riley
Moveset 3: Mason Ryan
Moveset 4: Ezekiel Jackson
Moveset 5: Michael McGillicutty
Moveset 6: Husky Harris/Bray Wyatt
Moveset 7: William Regal
Moveset 8: Tyson Kidd
Moveset 9: JTG
Moveset 10: John Morrison
Moveset 11: Chris Masters
Moveset 12: Vladimir Kozlov
Moveset 13: Chavo Guerrero
Moveset 14: MVP
Moveset 15: Batista
Moveset 16: Michelle McCool
Moveset 17: Melina
Moveset 18: Maryse
Moveset 19: Shelton Benjamin
Moveset 20: Charlie Haas
Moveset 21: Goldberg
Moveset 22: Kurt Angle
Moveset 23: Rob Van Dam
Moveset 24: Mr. Anderson
Moveset 25: Jeff Hardy
Moveset 26: Matt Hardy
Moveset 27: D'Angelo Dinero
Moveset 28: AJ Styles
Moveset 29: Ric Flair
Moveset 30: Roddy Piper

This works in numerous ways. Most of the superstars are unlocked through Attitude Mode. To unlock the characters from Attitude Mode, you must complete the Match Objectives and Historic Objectives to achieve the goal.